34254-52-9Relevant academic research and scientific papers
An Improved Synthesis of 2,3- and 3,4-Unsaturated Pyranosides: the Use of Microwave Energy
Baptistella, Lucia H. B.,Neto, Alana Z.,Onaga, Helena,Godoi, Eduardo A. M.
, p. 8407 - 8410 (1993)
Tipson-Cohen reactions of sugar derivatives containing contigous sulfonyloxy groups have been studied in a microwave oven.Considerable rate increases and high yields of the unsaturated products have been observed.
Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 3. Synthesis of (-)-Frontalin
Jarosz, Slawomir,Hicks, David R.,Fraser-Reid, Bert
, p. 935 - 940 (2007/10/02)
3-Deoxy-2-oxo glycosides with and without a C4 hydroxyl group are readily prepared from methyl α-D-glucopyranoside.Reaction with methylmagnesium iodide gives the C2 tertiary alcohol with an axially oriented methyl group.The epimeric tertiary alcohol can b
