34263-94-0Relevant academic research and scientific papers
Ruthenium-Catalyzed Tandem Carbene/Alkyne Metathesis/N-H Insertion: Synthesis of Benzofused Six-Membered Azaheterocycles
Padín, Damián,Saá, Carlos,Varela, Jesús A.
supporting information, (2020/03/30)
The Cp*RuCl-based catalyst enables expedient access to a variety of benzofused six-membered azaheterocycles from unprotected o-alkynylanilines and trimethylsilyldiazomethane through an unprecedent tandem carbene/alkyne metathesis/N-H insertion reaction. The transformation takes place under mild reaction conditions (room temperature, 15 min) and with excellent functional group tolerance. The synthetic utility of the final products and a mechanistic rationale are also discussed.
Synthesis and highly enantioselective hydrogenation of exocyclic enamides: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines
Zhou, Yong-Gui,Yang, Peng-Yu,Han, Xiu-Wen
, p. 1679 - 1683 (2007/10/03)
(Chemical Equation Presented) Highly enantioselective hydrogenation of exocyclic enamides, (Z)-3-arylidene-4-acyl-3,4-dihydro-2H-benzoxazines, was achieved in up to 98.6% ee by using Rh/(R,R)-Me-Duphos complex as the catalytic system. The absolute configu
The Asymmetrical Diacetylene Derivatives FBS/TFMBS and DNP/MNP: Synthesis and Solid State Properties
Strohriegl, P.,Gmeiner, J.,Mueller, I.,Gruner-Bauer, P.,Dormann, E.,Enkelmann, V.
, p. 491 - 498 (2007/10/02)
The synthesis of two new asymmetrical diacetylene (DA) derivatives is described: 1-(4-fluorobenzenesulfonyloxy)-6-(4-trifluoromethylbenzenesulfonyloxy)-2,4-hexadiyne (FBS/TFMBS) and 1-(2,4-dinitrophenoxy)-6-(4-methyl-2-nitrophenoxy)-2,4-hexadiyne (DNP/MNP
