342776-32-3Relevant academic research and scientific papers
Total synthesis of the immunosuppressant FR901483 via an amidoacrolein cycloaddition
Maeng, Jun-Ho,Funk, Raymond L.
, p. 1125 - 1128 (2001)
Matrix presented The total synthesis of the potent immunosuppressant FR901483 is described. In a key step, the intermolecular Diels-Alder cycloaddition of an amidoacrolein with 2-(triisopropylsilyloxy)-1,3-butadiene produced the desired 3-cyclohexene-1-ca
