342877-23-0

Basic information

• Product Name: (η5-C5H5)Fe(CO)2(η1-CH2CHCHCH2-P(C6H5)3) hexafluorophosphate
• CAS NO: 342877-23-0
• Molecular Weight: 638.309
• Mol File: 342877-23-0.mol

Chemical Properties

• CAS DataBase Reference: (η5-C5H5)Fe(CO)2(η1-CH2CHCHCH2-P(C6H5)3) hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-C5H5)Fe(CO)2(η1-CH2CHCHCH2-P(C6H5)3) hexafluorophosphate(342877-23-0)
• EPA Substance Registry System: (η5-C5H5)Fe(CO)2(η1-CH2CHCHCH2-P(C6H5)3) hexafluorophosphate(342877-23-0)

Safety Data

• Hazardous Substances Data: 342877-23-0(Hazardous Substances Data)

Upstream product

• 36119-40-1 (η5-C5H5)Fe(CO)2(η2-1,3-butadiene) hexafluorophosphate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

The synthesis, characterization and some reactions of cationic η2-(α,ω-diene) complexes of iron

The cationic iron η2-(α,ω-diene) complexes of the type. [(η5-C5H5)Fe(CO)2{η 2-(α,ω-diene)}]PF6, (diene = 1,3-butadiene: 1.4-pentadiene; 1.5-hexadiene; and 1.7-octadiene) were prepared by the reaction of η1-alkenyl compounds of the type [(η5C5H5)Fe(CO)2(η 1-alkenyl)] with the so-called trityl salt. (Ph3CPF6). The reactions of the η2-diene complexes with a number of nucleophiles give a range of products resulting from nucleophillic addition to the coordinated diene and/or displacement of the diene. The reaction with triethylamine results in deprotonation leading to the formation of [(η5-C5H5)Fe(CO)2(η 1-allyl)] complexes.