342909-16-4

Upstream product

• 342909-14-2 dimethyl (1'E,3'S)-2-(3'-acetoxy-4'-t-butyldiphenylsilyloxy-but-1'-enyl)-2-benzylmalonate 
• 342906-84-7 dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate 

Relevant academic research and scientific papers

Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part II. Scope and applications

An enantioselective synthesis of allylic esters has been achieved by a novel asymmetric alkylation of allylic gem-dicarboxylates. The catalyst derived from palladium(0) and R,R-1,2-di(2′-diphenylphosphinobenzamido)cyclohexene efficiently induced the alkyl