34301-54-7 Usage
Uses
Different sources of media describe the Uses of 34301-54-7 differently. You can refer to the following data:
1. AT can be used to functionalize folic acid based polyethylene glycol-maleimide which can be used in the development of gold nanorod (AuNR) based mixtures for spatiotemporal delivery of anticancer therapeutics. It can also be used with 1-octadecanethiol which forms SAM on palladium/aluminum oxide (Pd/Al2O3) which finds potential application as a controlled catalyst.
2. Displaceable Monolayers and Microdisplacement Printing: 1-Adamantanethiol Assembly and Applications
General Description
1-Adamantanethiol (AT) is a bulky caged hydrocarbon based thiol that has no free rotational configurations in its backbone. It forms a self-assembled monolayer (SAM) by attaching order close packed structured to the surface atoms.
Check Digit Verification of cas no
The CAS Registry Mumber 34301-54-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,3,0 and 1 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 34301-54:
(7*3)+(6*4)+(5*3)+(4*0)+(3*1)+(2*5)+(1*4)=77
77 % 10 = 7
So 34301-54-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H16S/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9,11H,1-6H2
34301-54-7Relevant articles and documents
Initiation in Photoredox C-H Functionalization Reactions. Is Dimsyl Anion a Key Ingredient?
Budén, María E.,Bardagí, Javier I.,Puiatti, Marcelo,Rossi, Roberto A.
, p. 8325 - 8333 (2017/08/23)
Previous studies have reported the arylation of unactivated arenes with ArX, base (KOtBu or NaOtBu), and an organic additive at high temperatures. Recently, we showed that this reaction proceeds in the absence of additives at rt but employs UV-vis light. However, details of mechanisms that can use a photoinduced base-promoted homolytic aromatic substitution reaction (photo-BHAS) have remained elusive until now. This work examines different mechanistic routes of the essential electron-transfer step (ET) of this reaction in order to identify a possible path for the formation of 1-adamantyl radicals from 1-haloadamantanes (initiation step). On the basis of photochemical and photophysical experiments and computational studies, we propose an unprecedented initiation step that could also be applied to other ET reactions performed in DMSO. For the first time, it is reported that dimsyl anion, formed from a strong base and DMSO (solvent), is responsible for inducing the initiation by a photo-BHAS process on alkyl halides.
