34303-81-6

Basic information

• Product Name: (Z)-3-Hexadecene
• Synonyms: (Z)-3-Hexadecene
• CAS NO: 34303-81-6
• Molecular Formula: C₁₆H₃₂
• Molecular Weight: 224.43
• Mol File: 34303-81-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 288.1°C at 760 mmHg
• Flash Point: 125.8°C
• Appearance: /
• Density: 0.784g/cm³
• Vapor Pressure: 0.00413mmHg at 25°C
• Refractive Index: 1.445
• CAS DataBase Reference: (Z)-3-Hexadecene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-Hexadecene(34303-81-6)
• EPA Substance Registry System: (Z)-3-Hexadecene(34303-81-6)

Safety Data

• Hazardous Substances Data: 34303-81-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H32/c1-3-5-7-9-11-13-15-16-14-12-10-8-6-4-2/h5,7H,3-4,6,8-16H2,1-2H3/b7-5-

Upstream product

• 74533-95-2 E-3-hexadecene 
• 103227-39-0 C₁₈H₃₂O₄ 

Relevant articles and documents

SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS (II). -PHOTOLYSIS OF UNSYMMETRICAL DIACYLPEROXIDES WITH ALKENYL-, HALO-, KETO-, CARBOXYL-GROUPS AND A CHIRAL α-CARBON. COMPARISON WITH THE MIXED KOLBE ELECTROLYSIS.

- Alkenoyl and functionalized alkanoyl dodecanoyl peroxides are prepared in 70 to 97 percent yield and photolyzed at -78 deg C.Thereby 4- to 10-alkenoyl and 4-alkynoyl peroxides afford good yields (56 - 68 percent) of unsymmetrical coupling products.Similarly α- to δ-haloalkanoyl, cholanoyl or 3- and 4-carboxyalkanoyl peroxides can be coupled (40 - 70 percent).The α-chiral diacyl peroxide 1s undergoes the photochemical coupling reaction with 80 percent retention of its configuration.The photolysis of diacyl peroxides at -78 deg C proves to be a favorable supplement of the Kolbe-electrolysis in cases, where the electrolysis fails or produces low yields.