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34314-83-5

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34314-83-5 Usage

Definition

ChEBI: A dihydrofuran that is 2,3-dihydrofuran substituted by a methyl group at position 4.

Check Digit Verification of cas no

The CAS Registry Mumber 34314-83-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,3,1 and 4 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 34314-83:
(7*3)+(6*4)+(5*3)+(4*1)+(3*4)+(2*8)+(1*3)=95
95 % 10 = 5
So 34314-83-5 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O/c1-5-2-3-6-4-5/h4H,2-3H2,1H3

34314-83-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-methyl-2,3-dihydrofuran

1.2 Other means of identification

Product number -
Other names Furan,2,3-dihydro-4-methyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:34314-83-5 SDS

34314-83-5Downstream Products

34314-83-5Relevant articles and documents

Gas-phase Protonation of Unsaturated Ethers: Experimental and Theoretical Study of 2,3- and 2,5-Dihydrofuran and Related Compounds

Bouchoux, Guy,Djazi, Faycal,Hoppilliard, Yannik,Houriet, Raymond,Rolli, Eric

, p. 209 - 214 (1986)

The protonation of 2,3- and 2,5-dihydrofuran is examined in gas-phase equilibrium proton transfer reactions conducted in an ion cyclotron resonance spectrometer.The thermodynamically favoured site of protonation in the two compounds is seen to be different: whereas the first isomer forms a carbocation upon protonation, the second isomer protonates on the oxygen atom an oxonium ion.The results obtained with substituted derivatives and with linear analogues confirm these conclusions.Molecular orbital calculations on the various structures for protonated bases are performed at the 4-31G level with correction for configuration interaction effects and at the 4-31G* level.The latter basis set provides the best results owing to the introduction of d-type orbitals on the oxygen atom.The calculation results substantiate the experimental observations and provide details on the molecular structure of the protonated species.

METHOD FOR PRODUCING COMPOUND HAVING ACID-LABILE GROUP

-

, (2008/06/13)

The present invention provides a process for producing a compound having a group represented by general formula (II): (wherein R1, R2, and R3 may be the same or different, and each represent a substituted or unsubstituted alkyl, a substituted or unsubstituted aryl, or a substituted or unsubstituted aralkyl, or R1 and R2 may bind to each other to form an alicyclic hydrocarbon ring together with the adjacent carbon atoms, or R2 and R3 may bind to each other to form a alicyclic heterocyclic ring together with the adjacent O-C-C that may have a substituent), which comprises allowing a compound having a hydroxyl group to react with halogenated alkyl ether represented by general formula (I): (wherein R1, R2, and R3 are the same as those defined above, respectively and X represents a halogen atom).

Highly Enantioselective Intermolecular Cu(I)-Catalyzed Cyclopropanation of Cyclic Enol Ethers. Asymmetric Total Synthesis of (+)-Quebrachamine

Temme, Oliver,Taj, Shabbir-Ali,Andersson, Pher G.

, p. 6007 - 6015 (2007/10/03)

A set of cyclic enol ethers derived from 2,3-dihydrofuran 35 and 3,4-dihydropyran 8 with a varying substitution pattern at the olefinic system were synthesized. Evans's ligand 5 with Cu(I)OTf was found to be an effective catalyst in the cyclopropanation reaction between cyclic enol ethers 14, 19, 28-31, and 33 and ethyl diazoacetate 6 to give diastereoselectivities up to exo/endo = 95:5 and enantioselectivities higher than 95% in nearly all cases. Because of the selective building of a quarternary carbon center and good yields in the formation of bicyclic structures 34c-h, the reaction was used as a key step in the asymmetric synthesis of (+)-quebrachamine 7, an indole alkaloid of the Aspidosperma family. After acid-induced ring opening of bicyclic compound 34f to lactone 40 followed by LiAlH4 reduction to the masked aldehyde 41, a reaction with tryptamine gave intermediate 42. This alcohol was efficiently converted into the indole alkaloid (+)-quebrachamine 7 in an overall yield of 37% starting from the chiral synthon 34f. Moreover it revealed the absolute configuration of the quarternary center of the cyclopropanation product 34f to be S.

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