343372-33-8

Basic information

• Product Name: 2,2'-[1-OXA-4,10,16-TRITHIA-7,13-DIAZACYCLOOCTADECANE-7,13-DIYLBIS(METHYLENE)]BIS-8-QUINOLINOL
• Synonyms: 2,2'-[1-OXA-4,10,16-TRITHIA-7,13-DIAZACYCLOOCTADECANE-7,13-DIYLBIS(METHYLENE)]BIS-8-QUINOLINOL
• CAS NO: 343372-33-8
• Molecular Formula: C32H40N4O3S3
• Molecular Weight: 624.88
• Mol File: 343372-33-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,2'-[1-OXA-4,10,16-TRITHIA-7,13-DIAZACYCLOOCTADECANE-7,13-DIYLBIS(METHYLENE)]BIS-8-QUINOLINOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-[1-OXA-4,10,16-TRITHIA-7,13-DIAZACYCLOOCTADECANE-7,13-DIYLBIS(METHYLENE)]BIS-8-QUINOLINOL(343372-33-8)
• EPA Substance Registry System: 2,2'-[1-OXA-4,10,16-TRITHIA-7,13-DIAZACYCLOOCTADECANE-7,13-DIYLBIS(METHYLENE)]BIS-8-QUINOLINOL(343372-33-8)

Safety Data

• Hazardous Substances Data: 343372-33-8(Hazardous Substances Data)

Usage

Central cage-like structure

The compound has a core structure that resembles a cage, which contains multiple nitrogen and sulfur atoms.

Nitrogen and sulfur atoms

These elements are present in the central cage-like structure, contributing to the compound's ability to coordinate with metal ions.

High potential for coordination with metal ions

The presence of nitrogen and sulfur atoms in the structure allows OTQ to form strong bonds with various metal ions.

Chelating ability

OTQ can chelate metal ions, which means it can form multiple bonds with a single metal ion, enhancing its stability and reactivity.

Versatility

The compound's structure and potential for metal coordination make it an interesting and adaptable compound for further research and development.

Upstream product

• 14510-06-6 2-formyl oxine 
• 343372-28-1 7,13-diaza-4,10,16-trithia-1-oxacyclooctadecane 
• 226211-71-8 bis<2-(α-chloroacetamido)ethyl> sulfide 
• 343372-25-8 7,13-diaza-1-oxa-4,10,16-trithiacyclooctadecane-6,14-dione 

Relevant articles and documents

Bis-8-hydroxyquinoline-armed diazatrithia-15-crown-5 and diazatrithia-16-crown-5 ligands: Possible fluorophoric metal ion sensors

The synthesis and preliminary photophysical properties of a series of diazatrithia-15-crown-5 and diazatrithia-16-crown-5 ligands containing two 8-hydroxyquinoline sidearms are reported. The ligands were prepared by a two-step process. First, diazatrithiacrown ethers 11 and 12 were prepared by treating bis(α-chloroamide) 5 with various dimercaptans followed by reduction using a boron-THF complex. Hydroxymethyl-substituted macrocycle 12 was rearranged to hydroxy-substituted diazatrithia-16-crown-5 in refluxing aqueous HCl. Macrocyclic diamines 11-13 were converted to either 5-chloro-8-hydroxyquinolin-7-ylmethyl-substituted diazatrithiacrown ethers 14-16 by a Mannich aminomethylation reaction or to 8-hydroxyquinolin-2-ylmethyl-substituted diazatrithiacrown ethers 17-19 by reductive amination using 8-hydroxyquinoline-2-carboxaldehyde. Preliminary photophysical studies show that ligands 16 and 19 exhibit increased fluorescence in the presence of Zn2+, indicating that these ligands could be chemical sensors for Zn2+.