3439-92-7

Basic information

• Product Name: 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene
• Synonyms: 1,4:5,8-Dimethanonaphthalene, 2-chloro-1,2,3,4,4a,5,8,8a-octahydro- (7CI,8CI,9CI)
• CAS NO: 3439-92-7
• Molecular Formula: C₁₂H₁₅Cl
• Molecular Weight: 194.7005
• Mol File: 3439-92-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 280.8°C at 760 mmHg
• Flash Point: 109.3°C
• Density: 1.21g/cm³
• Vapor Pressure: 0.00632mmHg at 25°C
• Refractive Index: 1.586
• CAS DataBase Reference: 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene(3439-92-7)
• EPA Substance Registry System: 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene(3439-92-7)

Safety Data

• Hazardous Substances Data: 3439-92-7(Hazardous Substances Data)

Upstream product

• 75-01-4 chloroethylene 
• 542-92-7 cyclopenta-1,3-diene 
• 33163-94-9 C₁₂H₁₄O 
• 7388-87-6 2ξ-Hydroxy-(4arH,8acH)-Δ⁶-octahydro-1t,4t:5c,8c-dimethano-naphthalin 

Downstream Products

• 83602-18-0 (1α,4α,4aβ,5α,8α,8aβ)-1,4,4a,5,8,8a-hexahydro-1,4:5,8-dimethanonaphthalene 

Relevant articles and documents

THE SYNTHESIS OF RIGID NORBORNYLOGS FOR THE PURPOSE OF STUDYING ORBITAL INTERACTIONS THROUGH BONDS

The synthesis of members of the series of rigid bichromophoric norbornylogs 4-8 is described.Dienes 4a and b were synthesized according to Scheme 1.Reductive dechlorination of 26-28 (Scheme 2) gave dienes 5b-d, respectively.Benzene annelation of the appropriate ene substrate, using tetrachlorodimethoxycyclopentadiene, as outlined in Scheme 3, gave the dibenzo compounds 6a-c.The dibromoquinodimethane intermediate 49 was trapped by the appropriate diene to give the bisnaphtho compounds 7a-c.The extended norbornylogs 8a and b were synthesized using a combination of metal catalyzed (2+2) cycloaddition of DMAD and (2+2+2) cycloaddition of quadricyclane to ene substrates (Scheme 5).The photoelectron spectra of some of the dienes are discussed in terms of through bond orbital interactions.