34411-93-3Relevant academic research and scientific papers
Studies in Pyranomethylchromones and Prenylated Pyranomethylchromones
Iyer, P. R.,Iyer, C. S. Rukmani,Prasad, K. J. Rajendra
, p. 535 - 538 (2007/10/02)
5,7-Dihydroxy-2-methylchromone (I) on prenylation with 2-methyl-3-buten-2-ol in the presence of BF3 etherate yields pulverin (II) and peucenin (III), which are separable by column chromatography.Cyclodehydrogenation of II with DDQ in benzene under reflux for 6 hr affords 6-(3,3-dimethylallyl)alloptaeroxylin (IV) and 10-(3,3-dimethylallyl)spatheliachromene (V) while prolonged refluxing (70 hr) yields in addition to IV and V, the bispyranochromone (VI) identified as spatheliabischromene.Pyranochromones IV, V and VI have also been synthesised by alternative routes.Alloptaeroxylin (VII) on prenylation with 2-methyl-3-buten-2-ol in the pres ence of BF3 etherate gives IV.Compound III undergoes cyclodehydrogenation with DDQ to give spatheliachromene (VIII) which on prenylation affords V.Acid-catalysed cyclisation of IV followed by NBS/DDQ dehydrogenation of the resultant dihydrodipyranochromone (IX) furnishes VI.
New Chromones from Cneoraceae
Epe, Bernd,Oelbermann, Ulrike,Mondon, Albert
, p. 757 - 773 (2007/10/02)
From Neochamaelea pulverulenta and Cneorum tricoccon the new and old chromones 1, 2, 4, 6, 8, 10, 11, 13, 18, 20, and 24 have been isolated.Syntheses of the natural (18, 20) and synthetic chromones (29, 30, and 34 - 39) are described.
