34427-30-0Relevant academic research and scientific papers
Chemoenzymatic total synthesis of cryptocaryalactone natural products
Reddy, Yarram Narasimha,Kumari, Tenkayala Navya,Thota, Pradeepkumar,Jyothi, Perla,Gupta, Ajay Kumar
, p. 160 - 162 (2017/12/15)
A new chemoenzymatic route for the preparation of cryptocaryalactones natural products using a kinetic resolution process as the key step is described. Novozyme-435 catalyzed hydrolysis of the prochiral (±)-monoester 7 afforded the precursors of cryptocar
Double Catalytic Kinetic Resolution (DoCKR) of Acyclic anti-1,3-Diols: The Additive Horeau Amplification
Merad, Jérémy,Borkar, Prashant,Caijo, Frédéric,Pons, Jean-Marc,Parrain, Jean-Luc,Chuzel, Olivier,Bressy, Cyril
, p. 16052 - 16056 (2017/11/21)
The concept of a synergistic double catalytic kinetic resolution (DoCKR) as described in this article was successfully applied to racemic acyclic anti-1,3-diols, a common motif in natural products. This process takes advantage of an additive Horeau amplif
Stereoselective total synthesis of (+)-(6R,2′S)-cryptocaryalactone and (-)-(6S,2′S)-epi cryptocaryalactone via asymmetric acetate aldol reaction
Yadav,Bhunia, Dinesh C.,Ganganna
, p. 2496 - 2499 (2012/06/16)
The total synthesis of (+)-(6R,2′S)-cryptocaryalactone and (-)-(6S,2′S)-epi cryptocaryalactone is reported based on asymmetric acetate aldol reaction. Still-Gennari reaction, Evans acetal intramolecular oxa-Michael reaction and lactonisation are the key s
Total synthesis of (+)-cryptocaryalactone and of a diastereoisomer of (+)-strictifolione via ring-closing metathesis (RCM) and olefin cross-metathesis (CM)
Sabitha, Gowravaram,Vangala, Bhaskar,Reddy, S. Siva Sankara,Yadav, Jhillu S.
experimental part, p. 329 - 338 (2010/05/15)
Ring-closing metathesis (RCM) and olefin cross-metathesis (CM) reactions were used as the key steps for the synthesis of (+)-cryptocaryalactone (1) and the first synthesis of the diastereoisomer 3 of (+)-strictifolione, starting from the commercially avai
A short stereoselective synthesis of (+)-(6R, 2′S)-cryptocaryalactone via ring-closing metathesis
Krishna, Palakodety Radha,Lopinti, Krishnarao,Reddy, K. L. N.
supporting information; experimental part, (2010/04/22)
A short stereoselective synthesis of (+)-(6R, 2′S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira's asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the
Synthesis of cryptocaryalactone, a 1,3-polyol-derived unsaturated lactone
Mori,Furukawa
, p. 2161 - 2163 (2007/10/02)
Cryptocaryalactone, a 1,3-polyol-derived α,β-unsaturated δ-lactone, has been synthesized in a stereocontrolled manner via the coupling reaction of a chiral dithiane with an epoxide and anti-stereoselective 1,3-asymmetric reduction of the derived hydroxy k
Syntheses and Absolute Configurations of (+)-(6R,2'S)-Cryptocaryalactone and (-)-(6S,2'S)-Epicryptocaryalactone
Meyer, Hartmut H.
, p. 977 - 981 (2007/10/02)
The naturally occuring (+)-cryptocaryalactone and the (-)-epicryptocaryalactone have been synthesized starting from the optically active aldehyde 1.The absolute configurations of these unsaturated lactones were determined by circular dichr
