344440-92-2Relevant academic research and scientific papers
Synthesis of gem-difluoromethylene building blocks through regioselective allylation of gem-difluorocyclopropanes
Munemori, Daisuke,Narita, Kent,Nokami, Toshiki,Itoh, Toshiyuki
supporting information, p. 2638 - 2641 (2014/06/09)
gem-Difluorocyclopropane derivatives react with allyltributylstannane in the presence of 2,2′-azobis(isobutyronitrile) to afford 1,6-dienes with a gem-difluoromethylene moiety at the allylic position. The reaction proceeds regioselectively with high yield
