344750-31-8

Basic information

• Product Name: Cyclobutanecarboxylic acid, 3-(methylthio)-, methyl ester (9CI)
• Synonyms: Cyclobutanecarboxylic acid, 3-(methylthio)-, methyl ester (9CI)
• CAS NO: 344750-31-8
• Molecular Formula: C7H12O2S
• Molecular Weight: 160.23398
• Product Categories: CARBOXYLICESTER
• Mol File: 344750-31-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclobutanecarboxylic acid, 3-(methylthio)-, methyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclobutanecarboxylic acid, 3-(methylthio)-, methyl ester (9CI)(344750-31-8)
• EPA Substance Registry System: Cyclobutanecarboxylic acid, 3-(methylthio)-, methyl ester (9CI)(344750-31-8)

Safety Data

• Hazardous Substances Data: 344750-31-8(Hazardous Substances Data)

Upstream product

• 4935-01-7 methyl bicyclo<1.1.0>butane-1-carboxylate 
• 5188-07-8 sodium thiomethoxide 

Relevant articles and documents

ADDITION TO BICYCLOBUTANE DERIVATIVES. VI. STEREOCHEMISTRY OF ADDITION OF SODIUM THIOLATES TO ACTIVATED BICYCLOBUTANES

In methanol sodium methanethiolate and thiophenolate add to methyl 1-bicyclobutanecarboxylate, 3-methyl-1-bicyclobutanecarboxylate, and 1-tricycloheptanecarboxylate exclusively at the central bicyclobutane C-C bond with nucleophilic attack at the β position to the methoxycarbonyl group.Here the bicyclic substrates exhibit poorly defined cis-stereoselectivity, while the tricyclic substrate exhibits distinct trans-stereoselectivity.The effect of the nature of the activating group on the stereoselectivity of addition of the anionoid nucleophiles to the activated bicyclobutanes is discussed.