34501-80-9Relevant articles and documents
Studies toward practical synthesis of (20S)-camptothecin family through catalytic enantioselective cyanosilylation of ketones: Improved catalyst efficiency by ligand-tuning
Yabu, Kazuo,Masumoto, Shuji,Kanai, Motomu,Curran, Dennis P.,Shibasaki, Masakatsu
, p. 2923 - 2926 (2007/10/03)
Enantioselective catalyst efficiency for the synthesis of the camptothecin family was improved through ligand-tuning. Key intermediates of two convergent syntheses of camptothecin (Curran's intermediate and Corey's intermediate) were obtained in up to 10 g scale through the catalytic enantioselective cyanosilylation of ketones.
Pig liver esterase catalyzed hydrolyses of diesters. A new route to the syntheses of achiral half-esters
Ager,Prakash
, p. 739 - 742 (2007/10/02)
Pig liver esterase catalyzed hydrolyses of diesters of alkanes, aromatic and heterocyclic compounds gave high yields of the corresponding half-esters under mild reaction conditions.
1-Furyl-3,4-dihydro-isoquinolines
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, (2008/06/13)
Compounds of the formula STR1 wherein R1 and R2, which may be identical to or different from each other, are each hydroxyl or lower alkoxy R3 is cyano or --CO--Y; Y is hydroxyl, lower alkoxy, or a primary or secondary, substituted or unsubstituted, aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic amino group; and non-toxic, pharmacologically acceptable acid addition salts thereof. The compounds as well as the salts are useful for the treatment of circulatory and coronary disorders.
A SIMPLE SYNTHESIS OF 3-SUBSTITUTED FURANS. THE PREPARATIONS OF DENDROLASIN, PERILLENE AND CONGENERS
Tanis, Steven P.
, p. 3115 - 3118 (2007/10/02)
The Grignard reagent 7, derived from 3-chloromethyl furan, reacts with various alkyl- and allylic halides, in the presence of Li2CuCl4, to provide high yields of 3-substituted furans.