345209-48-5Relevant academic research and scientific papers
A new C(1)-auxiliary for anomeric stereocontrol in the synthesis of alpha-sialyl glycosides.
Haberman,Gin
, p. 1665 - 1668 (2001)
The installation of the novel N,N-dimethylglycolamide ester auxiliary onto the C(1)-position of protected neuraminic acid donors allows for the exploitation of C(1)-neighboring group participation to generate sialoside conjugates with good to excellent al
Dehydrative sialylation with C2-hemiketal sialyl donors
Haberman, Jannine M.,Gin, David Y.
, p. 2539 - 2541 (2007/10/03)
(Matrix presented) A new method for sialylation involving the dehydrative coupling of sialyl donors with the reagent combination of (p-nitrophenyl)(phenyl) sulfoxide and triflic anhydride is reported. This process establishes sialyl C2-hemiketals as viabl
