345607-79-6Relevant articles and documents
R4*Tl3Cl and R6*Tl6Cl2 (R* =SitBu3) - The first compounds with larger clusters containing covalently linked thallium atoms
Wiberg, Nils,Blank, Thomas,Lerner, Hans-Wolfram,Fenske, Dieter,Linti, Gerald
, p. 1232 - 1235 (2001)
The largest Tl clusters to date with covalently linked Tl atoms are contained in the title compounds obtained from TlCl3 and two molar equivalents of NaSitBu3 in THF at -78°C. The structure of (SitBu3)6Tl6Cl2, which contains two Tl3Cl four-membered rings linked through the central Tl atoms and the Cl atoms, is depicted.
