345900-61-0Relevant articles and documents
Triethylamine-methanol mediated selective removal of oxophenylacetyl ester in saccharides
Rasool, Javeed Ur,Kumar, Atul,Ali, Asif,Ahmed, Qazi Naveed
, p. 338 - 347 (2021)
A highly selective, mild, and efficient method for the cleavage of oxophenylacetyl ester protected saccharides was developed using triethylamine in methanol at room temperature. The reagent proved successful against different labile groups like acetal, ketal, and PMB and also generated good yields of the desired saccharides bearing lipid esters. Further, we also observed DBU in methanol as an alternative reagent for the deprotection of acetyl, benzoyl, and oxophenylacetyl ester groups. This journal is
Syntheses and 1H- and 13C-Nuclear Magnetic Resonance Spectra of All Positional Isomers of Methyl Mono-O-tetradecanoyl-α- and β-D-Glucopyranosides
Yoshimoto, Kimihiro,Itatani, Yoshitaka,Shibata, Kanoko,Tsuda, Yoshisuke
, p. 208 - 219 (2007/10/02)
All the isomers of the mono-O-myristoyl derivative of methyl α- and β-D-glucopyranosides were unambiguously prepared, and their 1H- and 13C-NMR spectra are discussed in relation to the stereochemistry of the pyranose ring and ester grouping.The acylation