34591-37-2Relevant academic research and scientific papers
PROCESSES FOR THE PREPARATION OF ORTHO-ALLYLATED HYDROXY ARYL COMPOUNDS
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Paragraph 00280-00282; 00297, (2021/12/08)
The present application describes process for preparing an ortho-allylated hydroxy aryl compounds such as compounds of Formula (I) by reacting an allylic alcohol with a hydroxy aryl compound in the presence of aluminum compound selected from alumina and aluminum alkoxides and in a non-protic solvent wherein at least one carbon atom ortho to the hydroxy group in the hydroxy aryl compound is unsubstituted. The present application also includes compounds of Formula (I).
Gold-catalyzed rearrangement of substituted allyl aryl ethers
Vyvyan, James R.,Dimmitt, Heidi E.,Griffith, Jennifer K.,Steffens, Laura D.,Swanson, Rebecca A.
experimental part, p. 6666 - 6669 (2011/02/21)
Triphenylphosphinegold(I) complexes catalyze the Claisen-type rearrangement of aryl allyl ethers to the corresponding branched and linear products. The product distribution depends on the olefin geometry of the allylic ether. Stereochemical transfer experiments support an ionic mechanism.
Intramolecular excited-state interactions in phenol-styrene bicromophoric systems: A photochemical and photophysical study
Consuelo Jiménez,Miranda, Miguel A,Tormos, Rosa
, p. 115 - 120 (2007/10/03)
The intramolecular excited state interaction between phenol and styrene in a series of trans-2-cinnamylphenols bearing electron-donating substituents at the phenolic ring has been directly observed as an exciplex emission in acetonitrile. The photochemica
