345940-54-7Relevant academic research and scientific papers
Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate
Noda, Daisuke,Sunada, Yusuke,Hatakeyama, Takuji,Nakamura, Masaharu,Nagashima, Hideo
, p. 12231 - 12233 (2013/01/16)
Treatment of (η1-mesityl)2Fe(κ2- TMEDA) (1′) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the
