34649-46-2Relevant academic research and scientific papers
An Azidopiperideine -> Dihydrodiazepine Ring Expansion of the Fluorocarbon Class: Synthesis of Perfluoro-(1,4-dimethyl-2,3-diazacyclohepta-1,3-diene) via Thermolysis of Perfluoro-(6-azido-2,6-dimethyl-1-azacyclohexene)
Abed-Rabboh, Mohammad,Banks, Ronald E.,Beagley, Brian
, p. 1117 - 1118 (2007/10/02)
Flow pyrolysis of perfluoro-(6-azido-2,6-dimethyl-1-azacyclohexene) at ca. 380 deg C and 1 mmHg yields perfluoro-(1,4-dimethyl-2,3-diazacyclohepta-1,3-diene) (mainly) plus its isomers perfluoro-(1,5-dimethyl-6,7-diazabicyclohept-6-ene) and perfluoro-(2,4-dimethyl-1,3-diazacyclohepta-1,3-diene); the molecular geometry of the first of these products has been determined by gas-phase electron diffraction methods.
