346701-75-5

Basic information

• Product Name: (3R,4R,7S)-7-[(2R,3S)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-4-methyl-5-methylene-heptan-3-ol
• CAS NO: 346701-75-5
• Molecular Weight: 569.652
• Mol File: 346701-75-5.mol

Chemical Properties

• CAS DataBase Reference: (3R,4R,7S)-7-[(2R,3S)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-4-methyl-5-methylene-heptan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,7S)-7-[(2R,3S)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-4-methyl-5-methylene-heptan-3-ol(346701-75-5)
• EPA Substance Registry System: (3R,4R,7S)-7-[(2R,3S)-3-(2-Bromo-allyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-4-methyl-5-methylene-heptan-3-ol(346701-75-5)

Safety Data

• Hazardous Substances Data: 346701-75-5(Hazardous Substances Data)

Upstream product

• 346701-74-4 (1S,4R)-1-[(2S,3S)-3-(2-Bromo-allyl)-oxiranyl]-4-[(R)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-3-methylene-pentan-1-ol 
• 267236-44-2 [(2S,3S)-3-(2-Bromo-allyl)-oxiranyl]-methanol 
• 267236-34-0 (2R,3S)-5-bromo-2,3-epoxy-hex-5-enal 
• 224578-39-6 (4S)-4-benzyl-3-{(2S,3R)-3-hydroxy-5-[(4-methoxybenzyl)oxy]-2-methylpentanoyl}-1,3-oxazolidin-2-one 
• 171004-48-1 5-bromo-5-hexen-2-yn-1-ol 
• 128461-65-4 3-(p-methoxybenzyloxy)propanal 
• 346701-72-2 {(R)-3-[(R)-2-(4-Methoxy-phenyl)-[1,3]dioxan-4-yl]-2-methylene-butyl}-trimethyl-silane 
• 346701-73-3 (S)-2-[(R)-2-(4-Methoxy-phenyl)-[1,3]dioxan-4-yl]-propionic acid methyl ester 

Relevant articles and documents

Studies directed toward the syntheses of amphidinolides: Formal total synthesis of (-)-amphidinolide P

A formal total synthesis of (-)-amphidinolide P (1) has been achieved via an efficient convergent strategy for the stereoselective construction of the two advanced intermediates 2 and 3, used recently by Williams et al. in their synthesis of the same mole