34675-96-2Relevant academic research and scientific papers
Electron-rich Cations: Preparation and Hydride Reductions of the Cations 5-C5H5)>+, 5-C5H5)>+, and 5-C5H5)>+
Davies, Stephen G.,Simpson, Stephen J.,Felkin, Hugh,Tadj, Fatemeh,Watts, Oliver
, p. 981 - 986 (2007/10/02)
The synthesis of the cations 5-C5H5)>+, 5-C5H5)>+, and 5-C5H5)>+ as hexafluorophosphate salts is described.These cations are reduced regioselectively by lithium aluminium hydride to give the corresponding iron hydride species by direct attack on iron.The mechanisms of these reductions are discussed.
Hydride Reduction of the Cation 5-C5H5)Fe(triphos)>PF6: Direct Nucleophilic Attack on the Metal, and Hydrogen Exchange in the Product Hydride (η5-C5H5)FeH(triphos) (triphos = Ph2PCH2CH2PPhCH2CH2PPh2)
Davies, Stephen G.,Felkin, Hugh,Watts, Oliver
, p. 159 - 160 (2007/10/02)
Reduction of the cation 5-C5H5)Fe(triphos)>PF6 with lithium aluminium deuteride gives (η5-C5H5)FeD(triphos) which slowly undergoes H-D scrambling at 20 deg C (triphos = Ph2PCH2CH2PPhCH2CH2PPH2).
