34676-63-6

Basic information

• Product Name: [Rh(CO)Cl(P(C₆H₅)3)]2
• CAS NO: 34676-63-6
• Molecular Weight: 857.32
• Mol File: 34676-63-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(CO)Cl(P(C₆H₅)3)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(CO)Cl(P(C₆H₅)3)]2(34676-63-6)
• EPA Substance Registry System: [Rh(CO)Cl(P(C₆H₅)3)]2(34676-63-6)

Safety Data

• Hazardous Substances Data: 34676-63-6(Hazardous Substances Data)

Downstream Products

• 80492-53-1 [Rh(CO)(C₅H₄NNH₂)2(P(C₆H₅)3)]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₅H₄NNH₂)2(P(C₆H₅)3)](ClO₄) 
• 80492-55-3 [Rh(CO)(C₅H₄NCN)2(P(C₆H₅)3)]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₅H₄NCN)2(P(C₆H₅)3)](ClO₄) 
• 80492-57-5 [Rh(CO)(C₅H₄N)4(P(C₆H₅)3)]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₅H₄N)4(P(C₆H₅)3)](ClO₄) 
• 106500-79-2 {Ph2P(η5-C5H4)Rh(CO)}2 
• 106520-04-1 Ph2P(η5-C5H4)Rh(CO)(PPh3) 

Relevant articles and documents

Metallacycloalkanes, V. Preparation of a Rhodacycloheptane by Oxidative Coupling of 3,3-Dimethylcyclopropene to Rhodium(I) Complexes

The rhodacycloheptane derivative 2 is easily prepared in good yields from tris(triphenylphosphane)rhodium chloride or carbonylbis(triphenylphosphane)rhodium chloride and 3,3-dimethylcyclopropene.Spectroscopic data and X-ray analysis show that 2 is monomeric and has a syn,anti,syn structure.The hydrocarbon group of 2 is eliminated by reaction of 2 with CO to give hexamethyl-tris-?-homobenzene (5) and hexamethyl-tris-?-homotropone (4) in a ratio of 1:4.The X-ray structure of 4 is also given.