34679-27-1Relevant articles and documents
Alkynyl-Protected Au23 nanocluster: A 12-electron system
Wan, Xian-Kai,Yuan, Shang-Fu,Tang, Qing,Jiang, De-En,Wang, Quan-Ming
, p. 5977 - 5980 (2015)
A 23-gold-atom nanocluster was prepared by NaBH4-mediated reduction of a solution of PhC≡CAu and Ph3PAuSbF6 in CH2Cl2. The cluster composition was determined to be [Au23(PhC≡C)9(Ph3P)6]2+ and single-crystal X-ray diffraction revealed that the cluster has an unprecedented Au17 kernel protected by three PhC2-Au-C2(Ph)-Au-C2Ph motifs and six Ph3P groups. The Au17 core can be viewed as the fusion of two Au10 units sharing a Au3 triangle. Electronic structure analysis from DFT calculations suggests that the stability of this unusual 12-electron cluster is a result of the splitting of the superatomic 1D orbitals under D3h symmetry of the Au17 kernel. The discovery and determination of the structure of the Au23 cluster demonstrates the versatility of the alkynyl ligand in leading to the formation of new cluster compounds.
Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (phenylacetylido)(cyanido)aurate(I) monoacetone monohydrate, (PPN)[Au(CN)(CCC6H5)]·H2O·(CH3)2CO and bis(triphenylpho
Alsalme, Ali,Jaafar, Mohammed,Liu, Xue,Dielmann, Fabian,Hahn, F. Ekkehardt,Al-Farhan, Khalid,Reedijk, Jan
, p. 1 - 5 (2015)
Two new compounds containing the (acetylido)(cyanido)aurate(I) anion are reported. Their solid-state structures with the monocation PPN, bis(triphenylphosphane)iminium, are reported as a product containing a water molecule and an acetone molecule for the
1,1-Phosphaboration of CC and CC bonds at gold
Theulier, Cyril A.,García-Rodeja, Yago,Saffon-Merceron, Nathalie,Miqueu, Karinne,Bouhadir, Ghenwa,Bourissou, Didier
supporting information, p. 347 - 350 (2021/01/25)
The phosphine-borane iPr2P(o-C6H4)BFXyl2 (Fxyl = 3,5-(F3C)2C6H3) was found to react with gold(i) alkynyl and vinyl complexes via an original 1,1-phosphaboration process. Zwitterionic complexes resulting from Au to B transmetallation have been authenticated as key intermediates. X-ray diffraction analyses show that the alkynyl-borate moiety remains pendant while the vinyl-borate is side-on coordinated to gold. According to DFT calculations, the phosphaboration then proceeds in a trans stepwise manner via decoordination of the phosphine, followed by anti nucleophilic attack to the π-CC bond activated by gold. The boron center acts as a relay and tether for the organic group. This journal is