34699-28-0

Usage

Uses

Used in Organic Synthesis:
1-(4-Bromophenyl)-1,2,2-triphenylethylene is used as a key intermediate in organic synthesis for the production of various chemical compounds. Its unique structure allows for the formation of new chemical bonds and the synthesis of complex molecules, making it a valuable component in the chemical industry.
Used in Liquid Crystal Materials for Displays and Optoelectronic Applications:
1-(4-Bromophenyl)-1,2,2-triphenylethylene is used as a liquid crystal material in the development of advanced displays and optoelectronic devices. Its unique molecular structure and properties enable the manipulation of light, making it suitable for applications such as liquid crystal displays, optical switches, and other optoelectronic devices.
Used as a Fluorescent Probe for the Detection of Metal Ions:
1-(4-Bromophenyl)-1,2,2-triphenylethylene is used as a fluorescent probe for the detection and analysis of metal ions. Its ability to emit fluorescence upon interaction with metal ions makes it a valuable tool in analytical chemistry, environmental monitoring, and other fields where metal ion detection is crucial.
Used in Pharmaceutical Applications:
1-(4-Bromophenyl)-1,2,2-triphenylethylene is used as a potential anti-tumor agent and in the treatment of neurodegenerative diseases. Its biological activities have been studied, and it has shown promise in inhibiting tumor growth and providing neuroprotection. Further research is needed to fully understand its potential therapeutic applications and optimize its use in medicine.

Upstream product

• 1137-41-3 (4-aminophenyl)(phenyl)methanone 
• 589-87-7 1,4-bromoiodobenzene 
• 501-65-5 diphenyl acetylene 
• 98-80-6 phenylboronic acid 
• 881-42-5 diphenylmethyllithium 
• 101-81-5 Diphenylmethane 
• 2116-36-1 1-benzyl-4-bromo-benzene 
• 586-76-5 4-Bromobenzoic acid 
• 71-43-2 benzene 
• 1607-57-4 Triphenylvinyl bromide 
• 5467-74-3 4-Bromophenylboronic acid 
• 1016-77-9 3-bromobenzophenone 
• 108-86-1 bromobenzene 
• 119-61-9 benzophenone 

Downstream Products

• 1260865-91-5 4,4,5,5–tetramethyl–2–(4–(1,2,2–triphenylvinyl)phenyl)–1,3,2–dioxaborolane 
• 1227040-87-0 4-(1,2,2-triphenylvinyl)phenylboronic acid 
• 1225493-18-4 (2-(4-ethynylphenyl) ethane-1,1,2-triyl)tribenzene 
• 1351272-41-7 (2–(4–vinylphenyl)ethene–1,1,2–triyl)tribenzene 
• 1351272-44-0 C₂₈H₂₀Br₂ 
• 1289218-74-1 [1-(4-carbaldehydephenyl)-1,2,2-triphenyl]ethylene 
• 1262330-95-9 C₄₆H₃₄ 
• 1421768-47-9 (E)-4-(4-(1,1,2-triphenylvinyl)styryl)pyridine 
• 1416785-75-5 1,4-dimethyl-2,5-bis[4-(1,2,2-triphenylvinyl)phenyl]benzene 
• 1416785-74-4 1,4-bis(hexyloxy)-2,5-bis[4-(1,2,2-triphenylvinyl)phenyl]benzene 
• 1416785-73-3 1,5-bis[4-(1,2,2-triphenylvinyl)phenyl]naphthalene 
• 174676-07-4 9,10-bis(4-(1,2,2-triphenylvinyl)phenyl)anthracene 
• 1492771-69-3 4′-(1,2,2-triphenylvinyl)biphenyl-4-amine 
• 1426396-32-8 N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine 

Relevant academic research and scientific papers

High-Performance Emission/Color Dual-Switchable Polymer-Bearing Pendant Tetraphenylethylene (TPE) and Triphenylamine (TPA) Moieties

Electrofluorochromic (EFC) materials have aroused great interest owing to their interesting ability of tuning fluorescence in response to the applied potential. However, some crucial characteristics, such as response speed, fluorescence contrast, and swit

Synergistic effect between electroactive tetraphenyl-: P -phenylenediamine and AIE-active tetraphenylethylene for highly integrated electrochromic/electrofluorochromic performances

Switchable fluorescent materials have gained great attention due to their promising applications in sensors, memory devices and displays. However, further progress is hindered by the low fluorescence contrast, modest response speed and inferior long-term cycling stability. Based on a rational design strategy by combining a highly conjugated tetraphenyl-p-phenylenediamine (TPPA) unit and an aggregation induced emission (AIE)-active tetraphenylethylene (TPE) unit, we synthesized a novel diamine "N,N′-bis(4-aminophenyl)-N,N′-di(4-(1,2,2-triphenylethenyl)phenyl)-1,4-phenylenediamine" to construct an electro- and AIE-active polymer. In addition to the high efficiency solid-state fluorescence and the extremely stable redox properties, the resulting polymer TPE-TPPA-PA realized highly integrated emission/color dual-switchable properties, including multistage color-changing, high fluorescence on/off contrast up to 252, impressively rapid response rate (1.3/0.5 s for EC and 0.7/2.1 s for EFC processes) and excellent cycling stability over 10000 s. The demonstrated synergistic effect between stable electroactive TPPA and AIE-active TPE may provide a new pathway for further molecular design to realize high-performance emission/color dual-switchable materials.

Triphenylethylene benzimidazole derivatives with aggregation-induced emission (AIE) characteristics: An effect of the aryl linker and application in cell imaging

Three triphenylethylene benzimidazole derivatives TPT-BI, TPPT-BI and TPB-BI with aggregation-induced emission properties were synthesized, and the effect of connecting aromatic rings was studied. Among these TPT-based luminescent agents, TPT-BI showed th

Identification of the donor-substitution effect of tetraphenylethylene AIEgen: Synthesis, photophysical property analysis, and bioimaging applications

Various aggregation-induced emission luminogen (AIEgen) derivatives based on TPE (tetraphenylethylene) containing the electron-donating moiety (–NMe2, –OMe) and bromine (–Br) moiety were prepared, which are key intermediates for tuning the emis

Enantiomeric selectivity of ruthenium (II) chiral complexes with antitumor activity, in vitro and in vivo

Different enantiomers of chiral drugs show distinctive activities. Here, a pair of chiral ruthenium Λ-[Ru(phen)2(TPEPIP)]2+ (Λ-Ru), and Δ-[Ru(phen)2(TPEPIP)]2+ (Δ-Ru) (phen = 1,10-phenanthroline; TPEPIP = 2-(4′-(1,2,2-triphenylvinyl)-[1,1′-biphenyl]-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) compounds have been prepared and characterized. Both have aggregation-induced emission characteristics, although Λ-Ru exhibits much higher activity, towards duplex DNA extracted from SGC-7901 cancer cells. In vitro experiments demonstrate that both Λ-Ru and Δ-Ru can induce the apoptosis of tumor cells with Λ-Ru showing greater activity than Δ-Ru. Λ-Ru aggregates in the cell nucleus of SGC-7901 within 5 h which shows that nucleic acids may be the effective target of Λ-Ru. In vivo experiments with nude mice showed that Λ-Ru can inhibit the growth and proliferation of a tumor, in tumor-bearing mice as well as targeting the tumor site, as demonstrated by fluorescence. These results demonstrate the dual-function of Λ-Ru, which could be used for real-time visualization of a chemotherapeutic agent.

Biocompatible and noncytotoxic nucleoside-based AIEgens sensor for lighting-up nucleic acids

Aggregation-induced emission luminogens (AIEgens) have been used in biomacromolecules detection. Herein, TPE-dC and TPE-dU acted as the nucleoside-based AIEgens sensors in the first case, which can be used to detect ctDNA and rRNA in vitro and light up th

Tetraphenylethylene AIEgen bearing thiophenylbipyridine receptor for selective detection of copper(ii) ion

Highly emissive tetraphenylethylene chromophore appended thiophenylbipyridine pendant as a receptor (1) site has been successfully synthesized via a multistep reaction pathway. The synthesized chromophore 1 was well characterized by modern spectroscopy. I

Discotic liquid crystals with aggregation-induced emission properties based on tetraphenylethylene and triphenylene derivatives

A novel aggregation-induced emission active molecules (TP-Cn-PETPE, n = 4 and 10) were synthesized, which contain a tetraphenylethene derivative as the emission active moiety, a pentahexyloxytriphenylene core as the mesogenic unit and an alkoxy spacer. Ex

Halogen Bonding Tetraphenylethene Anion Receptors: Anion-Induced Emissive Aggregates and Photoswitchable Recognition

A series of tetraphenylethene (TPE) derivatives functionalized with highly potent electron-deficient perfluoroaryl iodo-triazole halogen bond (XB) donors for anion recognition are reported. 1H NMR titration experiments, fluorescence spectroscopy, dynamic light scattering measurements, TEM imaging and X-ray crystal structure analysis reveal that the tetra-substituted halogen bonding receptor forms luminescent nanoscale aggregates, the formation of which is driven by XB-mediated anion coordination. This anion-coordination-induced aggregation effect serves as a powerful sensory mechanism, capable of luminescence chloride sensing at parts per billion concentration. Furthermore, the doubly substituted geometric isomers act as unprecedented photoswitchable XB donor anion receptors, where the composition of the photostationary state can be modulated by the presence of a coordinating halide anion.

Fluorine-boron complex-based micromolecular photo-thermal reagent and preparation method and application thereof

The invention discloses a small-molecule photo-thermal reagent based on a fluorine-boron complex and a preparation method and application thereof. The structural formula of the small-molecule photo-thermal reagent is shown in the specification. The photo-thermal reagent with high photo-thermal conversion efficiency and near-infrared two-region absorption is synthesized by virtue of a simple and convenient preparation method and low-cost raw materials; meanwhile, an ideal treatment effect is achieved in anti-tumor application.