34764-16-4Relevant articles and documents
The HgF2-Assisted Addition of the CF3S Group to the CN Triple Bond
Geisel, Martin,Mews, Ruediger
, p. 1675 - 1678 (2007/10/02)
In the presence of HgF2 the sulfenyl chloride CF3SCl adds to the triple bond of ClCN to give (CF3S)2NCF3 (9).From CF3SCl and CF3CN or CCl3CN the mono-addition products CF3CF=NSCF3 (6) and CCl3CF=NSCF3 (12) are formed in high yield. 6 and 12 are readily oxidized by HgF2/X2 (X = Cl, Br) to give the sulfur(IV) derivatives C2F5N=S(F)CF3 (7) and CCl3CF2N=S(F)CF3 (17), respectively.