34772-26-4

Basic information

• Product Name: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3P)3PdCl}BF₄
• Synonyms: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3P)3PdCl}BF₄
• CAS NO: 34772-26-4
• Molecular Weight: 1015.55
• Mol File: 34772-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3P)3PdCl}BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3P)3PdCl}BF₄(34772-26-4)
• EPA Substance Registry System: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3P)3PdCl}BF₄(34772-26-4)

Safety Data

• Hazardous Substances Data: 34772-26-4(Hazardous Substances Data)

Upstream product

• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 

Downstream Products

• 96998-72-0 {PtPd₂Cl(P(C₆H₅)2)2(P(C₆H₅)3)3}⁽¹⁺⁾*BF₄^(1-)={PtPd₂Cl(P(C₆H₅)2)2(P(C₆H₅)3)3}BF₄ 
• 13965-03-2 bis-triphenylphosphine-palladium(II) chloride 
• 17830-50-1 [palladium⁽⁰⁾(triphenylphosphine)2(maleic anhydride)] 
• 18115-61-2 iodophenylbis(triphenylphosphine)palladium 
• 31989-57-8 bis(triphenylphosphine)palladium⁽⁰⁾ 

Relevant articles and documents

Preparation of Complexes Bearing N-Alkylated, Anionic or Protic CAACs Through Oxidative Addition of 2-Halogenoindole Derivatives

CAAC precursors 2-chloro-3,3-dimethylindole 1 and 2-chloro-1-ethyl-3,3-dimethylindolium tetrafluoroborate 2BF4 have been prepared and oxidatively added to [M(PPh3)4] (M=Pd, Pt). Salt 2BF4 reacts with [Pd(PPh3)4] in toluene at 25 °C over 4 days to yield complex cis-[3]BF4 featuring an N-ethyl substituted CAAC, two cis-arranged phosphines and a chloro ligand. Compound trans-[3]BF4 was obtained from the same reaction at 80 °C over 1 day. Salt 2BF4 reacts with [Pt(PPh3)4] to give cis-[4]BF4. The neutral indole derivative 1 adds oxidatively to [Pt(PPh3)4] to give trans-[5] featuring a CAAC ligand with an unsubstituted ring-nitrogen atom. This nitrogen atom has been protonated with py?HBF4 to give trans-[6]BF4 bearing a protic CAAC ligand. The PdII complex trans-[7]BF4 bearing a protic CAAC ligand was obtained in a one-pot reaction from 1 and [Pd(PPh3)4] in the presence of py?HBF4.