34774-93-1

Usage

Physical appearance

Yellow crystalline solid.

Usage

Commonly used in organic synthesis and as an intermediate in the production of dyes, agrochemicals, and pharmaceuticals.

Toxicity

Known to be toxic if ingested, inhaled, or comes into contact with the skin.

Health hazards

May cause irritation to the respiratory system and skin.

Handling and storage

It is important to handle and store this chemical with caution, following proper safety procedures and using appropriate protective equipment.

Disposal

It is important to dispose of 2-[(methylsulfanyl)methyl]-4-nitroaniline properly to avoid any environmental contamination or harm.

Upstream product

• 1516-60-5 4-nitrophenyl azide 
• 75-18-3 dimethylsulfide 
• 67-68-5 dimethyl sulfoxide 
• 100-01-6 4-nitro-aniline 
• 27691-52-7 S,S-dimethyl-N-(p-nitrophenyl)sulfilimine 

Relevant academic research and scientific papers

Benzo[c]isothiazole 2-Oxides: Three-Dimensional Heterocycles with Cross-Coupling and Functionalization Potential

A robust method for the synthesis of benzo[c]isothiazole 2-oxides has been developed providing a range of functionalized derivatives starting from anilines and DMSO. The reaction sequence can be performed on a gram scale and leads to products that can easily be modified by standard cross-coupling reactions. (Figure presented.).

Thermal Reaction of Arylnitrenes with Dimethyl Sulphide, Thioanisole, and Tetrahydrothiophene

The thermal decomposition of the aryl azides (1) into dimethyl sulphide (2), thioanisole (3), and tetrahydrothiophene (4) generally affords the 2-substituted anilines (5)-(7) in practicable yields by Sommelet-Hauser rearrangement of the intermediate N-arylsulphimides (11a-c) which result from arylnitrene attack at the sulphur atom of (2)-(4).This constitutes a potential synthetic procedure.

Aromatic dicarboxamides

N-(4-aminophenyl)-aromatic dicarboximides, e.g. those of the formula STR1 OR SALTS THEREOF ARE ANTICONVULSANTS.

Process for preparing azasulfonium halide salts

Preparing azasulfonium halide salt derivatives of an aniline by reacting a halogen with a non-carbonylic dihydrocarbon sulfide, a beta-carbonylic hydrocarbon sulfide, or a β-thio ester or amide to form a halogen: sulfur compound complex and then reacting the complex with an aniline to form the azasulfonium halide salts. The azasulfonium halide salts are useful as intermediates in processes for making ortho-alkylated anilines, indoles, and 2-oxindoles which have a variety of known uses.