34830-11-0

Basic information

• Product Name: EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
• Synonyms: TFMC-EU;TRIS(TRIFLUOROMETHYLHYDROXYMETHYLENE-D-CAMPHORATO)EUROPIUM(III);TRIS(3-TRIFLUOROACETYL-D-CAMPHORATO)EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO], EUROPIUM(III) DERIVATIVE;GDCL3:6H2O;EU(FACAM)3;EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
• CAS NO: 34830-11-0
• Molecular Formula: C36H42EuF9O6
• Molecular Weight: 893.66
• EINECS: 252-232-9
• Product Categories: Chiral Shift ReagentsStable Isotopes;Asymmetric Synthesis;Chiral Resolution Reagents;NMR - Buffers and Reagents;NMR Solvents and Reagents
• Mol File: 34830-11-0.mol
• Article Data: 0

Chemical Properties

• Melting Point: 195-198 °C(lit.)
• Boiling Point: 293.1°Cat760mmHg
• Flash Point: 131°C
• Appearance: /solid
• Density: g/cm³
• Vapor Pressure: 0.000187mmHg at 25°C
• Water Solubility: Soluble in chloroform. Insoluble in water.
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(CAS DataBase Reference)
• NIST Chemistry Reference: EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(34830-11-0)
• EPA Substance Registry System: EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(34830-11-0)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• F: 3-10
• TSCA: Yes
• Hazardous Substances Data: 34830-11-0(Hazardous Substances Data)

Usage

Chemical Properties

yellow to orange powder

Uses

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride. Also reactant involved in synthesis of europium acetyl camphorate phosphine oxide complexes and reactions with 1,10-N,N?-phenanthroline dioxide derivatives.

InChI:InChI=1/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;