34880-53-0Relevant academic research and scientific papers
Trinitroethyl - A functionality leading to energetic compounds with high nitro content
Gao, Haixiang,Shreeve, Jean'Ne M.
, p. 24874 - 24880 (2014/07/07)
Synthesis, characterization, and thermolysis studies of new polynitro compounds with good oxygen balance are reported. These compounds have been fully characterized by IR, NMR, elemental analysis, differential scanning calorimetry (DSC), density, and impact sensitivity measurements. Additionally, the structure of 2,2,2-trinitro-N-2,2,2-trinitroethylidene-ethanamine (9) was confirmed by single-crystal X-ray diffraction. Based on experimental and calculated values, the properties of the new polynitro compounds, such as decomposition temperatures (102.7-154.4 °C), oxygen balance (-26.7-30.5%), detonation pressures (21.4-36.1 GPa) and velocities (7368-8749 ms-1), and impact sensitivities (3-29 J), were obtained.
Experimental and theoretical studies on some energetic functionalized trimethylamine derivatives
Klapoetke, Thomas M.,Krumm, Burkhard,Scherr, Matthias,Xaver Steemann,Banert, Klaus,Joo, Young-Hyuk
experimental part, p. 11341 - 11345 (2010/05/02)
The synthesis and structural properties (from X-ray diffraction or B3LYP/6-31G(d) calculations) of three energetic compounds derived from tris(chloromethyl)amine and of tris(chloromethyl)amine itself were investigated and compared to those of compounds with similar structures. The compounds have almost planar NC3 units at their amine center, and the substituents bound to the CH2 groups tend to be reactive towards further substitution. Multiple hyperconjugation was used to explain these observations.
Novel transformations of nitraminodiol diacetates
Fedorov
, p. 722 - 723 (2007/10/03)
A novel scission reaction of nitraminodiol diacetates of the formula AcO[CH2N(NO2)]xCH2OAc (x = 1-4) in concentrated sulfuric acid to form formaldehyde, nitramide, and 2-nitro-2-azapropane-1,3-diol disulfate was found.
