34884-49-6Relevant academic research and scientific papers
The heterolytic and the homolytic cleavage of the oxygen-nitrogen bond in O,N-diacylarylhydroxylamines
Bassoli, Angela,Gregorio, Giuseppina Di,Galliani, Guido,Riboldi, Massimo,Rindone, Bruno,et al.
, p. 293 - 297 (2007/10/02)
Two O,N-diacylarylhydroxylamines were thermolysed in different solvents and first order rate constants and activation parameters were calculated.A six-membered transition state is suggested in acetonitrile, radical pairs or ion pairs are suggested in the other solvents.Photolysis of five of these compounds gave a homolytic reaction pattern.
