349552-19-8Relevant academic research and scientific papers
Synthesis and reactivity of fluoro complexes. Part 1. Cyclooctadiene rhodium(I) complexes
Vicente,Gil-Rubio,Bautista
, p. 2636 - 2637 (2001)
The systhesis of [RhF(COD)]n and its triphenylphosphine adduct 2, and a preliminary study of the reactivity of 2 are reported. The reactivity of the Rh-F-bond is illustrated by the reactions that lead to compounds 5 and 6. Compound 5 is the first triflouromethyl Rh(1) complex characterized by monocrystal X-ray diffraction. Both compounds 2 and 6 are initiators of the polymerization of phenylacetylene.
