349580-76-3Relevant academic research and scientific papers
Facile syntheses of 4-(2-cyanoethylthio)-1,3-dithiole-2-thione and new electron donors with two TTF units and compounds with bis(1,3-dithiole-2-thione) groups
Jia, Chunyang,Zhang, Deqing,Guo, Xuefeng,Wan, Shuhui,Xu, Wei,Zhu, Daoben
, p. 2177 - 2182 (2002)
The synthetic conditions for the preparation of 4-(2-cyanoethylthio)-1,3-dithiole-2-thione (1) from TBA2?[Zn(dmit)2] were studied. Compound 1 was used to synthesize new electron donors with two tetrathiafulvalene (TTF) units. Other i
A new approach to 4-alkylthio-1,3-dithiole-2-thione: An unusual reaction of a zinc complex of 1,3-dithole-2-thione-4,5-dithiolate
Jia, Chunyang,Zhang, Deqing,Xu, Wei,Zhu, Daoben
, p. 1941 - 1943 (2007/10/03)
(formula presented) A new and facille approach to 4-alkylthio-1,3-dithiole-2-thione starting from easily accessible reactants was described. This approach was based on the unusual reaction of a zinc complex of 1,3-dithiole-2-thione-4,5-dithiolate with electrophilic reagents in the presence of 3-picolyl chloride hydrochloride/or 4-picolyl chloride hydrochloride/or pyridine hydrochloride.
