349606-50-4

Basic information

• Product Name: C₅H₅Mn(CO)2Fe(CO)3CC₆H₅SeC₆H₅
• Synonyms: C₅H₅Mn(CO)2Fe(CO)3CC₆H₅SeC₆H₅
• CAS NO: 349606-50-4
• Molecular Weight: 561.114
• Mol File: 349606-50-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅H₅Mn(CO)2Fe(CO)3CC₆H₅SeC₆H₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₅H₅Mn(CO)2Fe(CO)3CC₆H₅SeC₆H₅(349606-50-4)
• EPA Substance Registry System: C₅H₅Mn(CO)2Fe(CO)3CC₆H₅SeC₆H₅(349606-50-4)

Safety Data

• Hazardous Substances Data: 349606-50-4(Hazardous Substances Data)

Upstream product

• 17685-52-8 triiron dodecarbonyl 
• 645-96-5 Benzeneselenol 

Relevant articles and documents

Remarkable reactions of cationic carbyne complexes of manganese and rhenium with diiron anions [Fe2(μ-CO)(μ-SeR)(CO)6]-. A route to RSe-bridged dimetal bridging carbene complexes

The reactions of cationic carbyne complexes of manganese and rhenium, [η-C5H5(CO)2M≡CC6 H5]BBr4 (1, M = Mn; 2, M = Re), with diiron anionic compounds [Et3NH][Fe2(μ-CO) (μ-SeR)(CO)6] (3, R = C6H5; 4, R = p-CH3C6H4) in THF at low temperature gave the dimetal bridging carbene complexes [MFe{μ-C(SeR)C6H5} (CO)5(η-C5H5)] (10, M = Mn, R = C6H5); 11, M = Mn, R = p-CH3C6H4; 13, M = Re, R = C6H5; 14, M = Re, R = (p-CH3C6H4), [η-C5H5M(CO)3] (7, M = Mn; 12, M = Re), and [Fe2(μ-SeR)2(CO)6] (8, R = C6H5; 9, R = p-CH3C6H4). Complexes 1 and 2 also react with [MgBr][Fe2(μ-CO) (μ-SeC2H5)(CO)6] (5) to produce [Fe2(μ-SeC2H5)2(CO)6] (15) and dimetal bridging carbene complexes [MnFe{μ-C(SeC2H5)C6H5} (CO)5(η-C5H5)] (17) and [ReFe{μ-C(SeC2H5)C6H5} (CO)5(η-C5H5)] (18), respectively. 2 reacts similarly with [MgBr][Fe2(μ-CO)(μ-SeC4H9-n) (CO)6] (6) to give [Fe2(μ-SeC4H9-n)2(CO)6 ] (16) and a Re-Fe bridging carbene complex [ReFe{μ-C(SeC4H9-n)C6H5}(CO) 5(η-C5H5)] (19), while the analogous reaction of 1 with 6 produced an unexpected trimetal bridging carbyne complex [MnFe2(μ-H)(μ-CO)2(μ3 -CC6H5(CO)6) (η-C5H5)] (20). The structures of complexes 9, 10, 13, 18, and 20 have been established by X-ray diffraction studies.