350027-05-3Relevant academic research and scientific papers
Preparation of enantiopure chiral amino- [D1]methyllithium compounds and determination of their micro- and macroscopic configurational stabilities
Kapeller, Dagmar C.,Hammerschmidt, Friedrich
experimental part, p. 5729 - 5739 (2009/12/29)
Chiral amino-[D1]methyllithiums have been tested with regard to their microscopic and macroscopic configurational stabilities. The N-Boc-N-diethoxyphosphinyl-sub-stituted analogue immediately rearranged, showing complete retention of configuration at up t
An expeditious one-pot synthesis of diethyl N-Boc-1-aminoalkylphosphonates
Klepacz, Anna,Zwierzak, Andrzej
, p. 1079 - 1080 (2007/10/03)
A general one-pot, purification-free synthesis of diethyl N-Boc-1-aminoalkylphosphonates has been developed. The procedure involves base-catalyzed Michael-type addition of sodium diethyl phosphite to N-Boc imines generated in situ by the action of sodium
