350036-89-4Relevant articles and documents
Tandem polar/radical crossover sequences for the formation of fused and bridged bicyclic nitrogen heterocycles involving radical ionic chain reactions, and alkene radical cation intermediates, performed under reducing conditions: Scope and limitations
Crich, David,Ranganathan, Krishnakumar,Neelamkavil, Santhosh,Huang, Xianhai
, p. 7942 - 7947 (2007/10/03)
It is demonstrated that phosphorylated forms of β-nitro alcohols provide an excellent means of entry into β-(phosphatoxy)alkyl radicals on exposure to tributyltin hydride and AIBN in benzene at reflux. These radicals then undergo heterolytic cleavage of t