35016-92-3Relevant academic research and scientific papers
Nitrosocarbonyl Carbohydrate Derivatives: Hetero Diels-Alder and Ene Reaction Products for Useful Organic Synthesis
Corti, Marco,Leusciatti, Marco,Moiola, Mattia,Mella, Mariella,Quadrelli, Paolo
, p. 574 - 586 (2020/10/06)
The generation and trapping of two new nitrosocarbonyl intermediates bearing carbohydrate-based chiral substituents is achieved by the mild oxidation of the corresponding nitrile oxides with tertiary amine N -oxides. Their capture with suitable dienes and alkenes afforded the corresponding hetero Diels-Alder cycloadducts and ene adducts from fair to excellent yields. The entire methodology looks highly promising by the easy conversion of aldoximes into hydroxymoyl halides, widening the access to nitrosocarbonyls, versatile tools in organic synthesis.
Synthesis and biological activities of novel isoxazoline-linked pseudodisaccharide derivatives
Zhang, Pingzhu,Wei, Chao,Wang, Enkai,Wang, Wei,Liu, Ming,Yin, Qingmei,Chen, Hua,Wang, Kerang,Li, Xiaoliu,Zhang, Jinchao
experimental part, p. 7 - 16 (2012/05/04)
A series of novel isoxazoline linked pseudodisaccharide derivatives were regiospecifically synthesized by 1,3-dipolar cycloaddition of α-allyl-C-glycopyranosides and sugar-derived nitrile oxides with good yields. The structures of the compounds were chara
