350253-67-7Relevant academic research and scientific papers
Sterically fixed dithiolate ligands and their zinc complexes: Derivatives of 1,8-dimercaptonaphthalene
Tesmer, Markus,Vahrenkamp, Heinrich
, p. 1183 - 1188 (2001)
The synthesis of two new dithiols, 1,8-dimercapto-2,7-di(tert-butyl)naphthalene (H2L1) and 1,8-dimercaptonaphthoic anhydride (H2L2), is described. They react with diethylzinc to yield the polymeric complexes L1Zn and L2Zn. L1Zn dissolves in the presence of pyridine to form [L1Zn·py]x, which is presumed to be dimeric. Both L1Zn and L2Zn react with neocuproin. Structure determinations have confirmed the tetrahedral ZnN2S2 coordination in the resulting LZn·neo complexes.
