35036-32-9Relevant academic research and scientific papers
Cerium(IV), as a selective and efficient catalyst for alcoholyses of allylic and tertiary benzylic alcohols
Iranpoor, Nasser,Mothaghineghad, Enayatholah
, p. 1859 - 1870 (2007/10/02)
An efficient and selective method is described for the catalytic conversion of allylic, and tertiary benzylic alcohols into their corresponding ethers in the presence of Ce(IV) under solvolytic and non- solvolytic conditions.
ARYL REARRANGEMENT ON THE PHOTOLYSIS OF 2-ARYL-2-ETHOXY-2-PHENYLETHYL CABALOXIME.
Tada,Inoue,Okabe
, p. 1420 - 1423 (2007/10/02)
The photolysis of 2-aryl-2-ethoxy-2-phenylethyl cobaloxime followed by hydrolysis gave two kinds of substituted 1,2-diphenylethanones arising via phenyl or substituted-phenyl migration. The substituent effect on the aryl rearrangement is similar to that on the reported neophyl rearrangement, and the rearrangement takes place by a radical mechanism without the deep involvement of cobaloxine(II).
