350508-46-2Relevant academic research and scientific papers
Diastereoselective tandem 6-exo carbolithiation intramolecular ring opening in (-)-8-aminomenthol-derived perhydrobenzoxazines. A new synthesis of enantiopure 4-substituted tetrahydro isoquinolines and 2-azabenzonorbornanes
Pedrosa,Andres,Iglesias,Perez-Encabo
, p. 1817 - 1821 (2007/10/03)
Aryllithiums prepared by bromine - lithium interchange in chiral 2-(o-bromophenyl)-substituted perhydro-1.3-benzoxazines participate in the intramolecular 6-exo carbolithiation reaction with unactivated double bonds attached to the nitrogen substituent of
