350791-66-1

Basic information

• Product Name: spiro[1'(3',5'-diphenylcyclohexadien-4'-one)-1',61-methano[60]fullerene]
• CAS NO: 350791-66-1
• Molecular Weight: 964.953
• Mol File: 350791-66-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: spiro[1'(3',5'-diphenylcyclohexadien-4'-one)-1',61-methano[60]fullerene](CAS DataBase Reference)
• NIST Chemistry Reference: spiro[1'(3',5'-diphenylcyclohexadien-4'-one)-1',61-methano[60]fullerene](350791-66-1)
• EPA Substance Registry System: spiro[1'(3',5'-diphenylcyclohexadien-4'-one)-1',61-methano[60]fullerene](350791-66-1)

Safety Data

• Hazardous Substances Data: 350791-66-1(Hazardous Substances Data)

Upstream product

• 10368-54-4 2,6-diphenyl-1,4-benzoquinone diazide 
• 99685-96-8 fullerene-C₆₀ 

Relevant articles and documents

Reductive electrochemistry of spiromethanofullerenes

The synthesis and electrochemical properties of spiromethanofullerenes 1-6 are described. The syntheses were achieved via the diazomethane route, and the regioisomeric distribution of bis-adducts 3 was determined by 1H NMR, UV-vis, and HPLC analysis. The electrochemistry of these compounds in dichloromethane exhibits, besides several reversible reductions, some irreversible waves. Reductive electrolysis of 1 and 3-5 in dichloromethane leads to the removal of the addend and thus to the formation of C60. Reductive electrolysis of 1, 2 and 6 in dichloromethane leads to a different reaction, which we tentatively assign to a reaction with the solvent to form fullerene-CH2Cl products. Electrolyses in the less reactive solvent THF lead to adduct removal for 1 and 3-5. Interestingly, significant formation of bis-adducts from the corresponding monoadducts was observed for 4 and 5. These electrochemically induced reactions, namely addend removal, reaction with the solvent, and addend transfer are influenced by the structure of the addend and by the choice of solvent.