350987-69-8

Basic information

• Product Name: (4R)-benzyl-3-[(3S)-(tert-butyldimethylsilanyloxy)-(2R)-vinylhex-5-enoyl]oxazolidin-2-one
• Synonyms: (4R)-benzyl-3-[(3S)-(tert-butyldimethylsilanyloxy)-(2R)-vinylhex-5-enoyl]oxazolidin-2-one
• CAS NO: 350987-69-8
• Molecular Weight: 429.632
• Mol File: 350987-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R)-benzyl-3-[(3S)-(tert-butyldimethylsilanyloxy)-(2R)-vinylhex-5-enoyl]oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-benzyl-3-[(3S)-(tert-butyldimethylsilanyloxy)-(2R)-vinylhex-5-enoyl]oxazolidin-2-one(350987-69-8)
• EPA Substance Registry System: (4R)-benzyl-3-[(3S)-(tert-butyldimethylsilanyloxy)-(2R)-vinylhex-5-enoyl]oxazolidin-2-one(350987-69-8)

Safety Data

• Hazardous Substances Data: 350987-69-8(Hazardous Substances Data)

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 350987-66-5 (4R)-benzyl-3-((3S)-hydroxy-(2R)-vinylhex-5-enoyl)oxazolidin-2-one 
• 151215-01-9 (4R)-3-((E)-2-BUTENOYL)-4-(PHENYLMETHYL)-2-OXAZOLIDINONE 

Downstream Products

• 350987-93-8 (3aS,4R,5R,6R,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-6-hydroxy-4-(2-nitro-phenylselanylmethyl)-hexahydro-cyclopentaoxazol-2-one 
• 350987-78-9 [8S,9S]-(5S)-(tert-butyldimethylsilanyloxy)-(7S)-iodo-1-(toluene-4-sulfonyl)hexahydrocyclopenta[d][1,3]oxazin-2-one 
• 350987-79-0 [8S,9S]-(5S)-(tert-butyldimethylsilanyloxy)-1-(toluene-4-sulfonyl)-4,4a,5,7a-tetrahydro-1H-cyclopenta[d][1,3]oxazin-2-one 
• 350987-77-8 C₂₀H₃₁NO₅SSi 
• 350987-72-3 (4R)-benzyl-3-[(1R,5S)-5-(tert-butyldimethylsilanyloxy)cyclopent-2-enecarbonyl]oxazolidin-2-one 

Relevant articles and documents

Formal total synthesis of (+)-trehazolin. Application of an asymmetric aldol-olefin metathesis approach to the synthesis of functionalized cyclopentenes

An asymmetric synthesis of the aminocyclopentitol pseudosugar of trehazolin has been completed. The synthesis hinges on an asymmetric aldol-ring closing metathesis strategy to construct the five-membered ring with control of both the relative and absolute stereochemistry.