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3aH-Cyclopenta[b]furan-3a-ethanol, 2-ethoxyhexahydro-alpha-methyl, (2R,3aS,6aR)-rel-(9CI) is a complex organic compound with a unique molecular structure. It is a derivative of cyclopenta[b]furan, a heterocyclic compound consisting of a five-membered ring with one oxygen atom and one carbonyl group. The compound features a 3a-ethanol group, which is a hydroxyl group attached to a carbon atom in the 3a position. Additionally, it has a 2-ethoxyhexahydro-alpha-methyl group, indicating the presence of an ethoxy group and a hexahydro (six-carbon) chain with a methyl group at the alpha position. The stereochemistry of the compound is defined by the (2R,3aS,6aR)-rel configuration, which specifies the arrangement of atoms in three-dimensional space. 3aH-Cyclopenta[b]furan-3a-ethanol,2-ethoxyhexahydro-alpha-methyl-,(2R,3aS,6aR)-rel-(9CI) is primarily of interest in the field of organic chemistry, particularly in the synthesis of complex molecules and the study of stereochemistry.

351010-32-7

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351010-32-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 351010-32-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,1,0,1 and 0 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 351010-32:
(8*3)+(7*5)+(6*1)+(5*0)+(4*1)+(3*0)+(2*3)+(1*2)=77
77 % 10 = 7
So 351010-32-7 is a valid CAS Registry Number.

351010-32-7Relevant academic research and scientific papers

Stereocontrolled formation of spiro enones by radical cyclization of bromo acetals

Clive, Derrick L.J.,Huang, Xiaojun

, p. 3845 - 3858 (2001)

Aldol condensation of ketones with 2-[[(1,1-(dimethylethyl)diphenylsilyl]oxy]propanal (7), dehydration, NaBH4 reduction and treatment of the resulting alcohols with ethyl vinyl ether in the presence of NBS gives bromo acetals (e.g. 11) that undergo 5-exo-trigonal radical cyclization, affording compounds that are easily converted into spiro enones (e.g. 16). The stereochemistry at the spiro center is controlled by the stereochemistry at the hydroxyl-bearing carbon of the intermediate alcohol.

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