35108-31-7

Basic information

• Product Name: 4,5-dimethyl-2-(tributylstannylsulfanyl)-thiazole
• Synonyms: 4,5-dimethyl-2-(tributylstannylsulfanyl)-thiazole
• CAS NO: 35108-31-7
• Molecular Weight: 434.298
• Mol File: 35108-31-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,5-dimethyl-2-(tributylstannylsulfanyl)-thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5-dimethyl-2-(tributylstannylsulfanyl)-thiazole(35108-31-7)
• EPA Substance Registry System: 4,5-dimethyl-2-(tributylstannylsulfanyl)-thiazole(35108-31-7)

Safety Data

• Hazardous Substances Data: 35108-31-7(Hazardous Substances Data)

Upstream product

• 688-73-3 tri-n-butyl-tin hydride 

Relevant articles and documents

Efficiency of alkoxyl radical product formation from 5-substituted 3-alkoxy-4-methylthiazole-2(3H)-thiones

In a comparative study, reactions between 5-(p-methoxyphenyl)-substituted 3-alkoxy-4-methylthiazole-2(3H)-thiones and appropriate mediators (BrCCl3, Bu3SnH) provided higher yields of alkoxyl radical products (δ-bromohydrins, cyclic ethers, carbonyl compounds) than respective transformations of 5-phenyl- and 5-methyl-substituted derivatives. The unusual selectivity of applied thiohydroxamates to furnish products of O-alkylation, even upon treatment with soft carbon electrophiles, and the marked propensity of 3-alkoxy-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thiones to crystallize, facilitated preparation and purification of the new family of alkoxyl radical precursors in a noteworthy manner.