35113-75-8Relevant academic research and scientific papers
Masked acylation of m-Dinitrobenzene and deriviatives with nitroalkanes under basic conditions: Nitromethylation and α-(hydroxyimino)alkylation
Kawakami,Suzuki
, p. 1157 - 1160 (1999)
m-Dinitrobenzene and derivatives react with nitromethane or some other primary nitroalkanes in the presence of lithium tert-butoxide in 1,3- dimethyl-2-imidazolizinone (DMI) at room temperature, giving the corresponding 4-nitromethyl and 4-[1-(hydroxyimino)alkyl] derivatives, respectively, in moderate yields. These products are smoothly converted to the corresponding carbonyl compounds by oxidative Nef reaction using ozonized oxygen.
Radical ion reactions of carbanions derived from 4-nitro-, 2,4-dinitro-, and 2,4,6-trinitrotoluenes with polynitroalkanes
Makarevich,Shcherbinin,Bazanov,Tselinskii
, p. 684 - 692 (2007/10/03)
4-Nitro-and 2,4-dinitrotoluenes react with tetranitro-and halotrinitromethanes in the presence of bases to give the corresponding nitro-substituted 1,2-diphenylethanes and stilbenes. Reactions of 2,4,6-trinitrotoluene with fluorotrinitromethane, N,N-dinitrotnethylamine, and tert-butyl and isopropyl nitrates result in formation of α,2,4,6-tetranitrotoluene; with chlorotrinitromethane, 2,4,6-trinitrobenzyl chloride is formed.
FLUORINATION OF ANIONIC ?-COMPLEXES BY CESIUM FLUOROXYSULFATE
Gakh, A. A.,Romaniko, S. V.,Ugrak, B. I.,Fainzil'berg, A. A.
, p. 1432 - 1436 (2007/10/02)
Anionic ?-complexes and related structures react with cesium fluoroxysulfate to give predominantly the C-fluoro derivatives: fluoronitrocyclohexadienes or substituted fluoronitrobenzenes.Oxidation or degradation of a complex to form substituted nitrobenzenes is also possible.The balance between all these processes is determined by the structure of the original complex.
