351326-73-3Relevant articles and documents
Syntheses and x-ray crystal structures of new copper(I) and silver(I) complexes containing thione ligands
Ghassemzadeh, Mitra,Adhami, Forough,Heravi, Majid M.,Taeb, Abas,Chitsaz, Soheila,Neumueller, Bernhard
, p. 815 - 819 (2001)
The reaction of [(Ph3P)2CuCl]2 with 4-amino-6-methyl-1,2,4-triazine-thione-5-one (AMTTO, 1) in methanol and further recrystallization from methanol/acetone solution gives [(C4H4N3SON(=CMe2)Cu(PPh 3)2Cl] (2) as a neutral complex. [(C4H4N3SON(=CMe2)Ag(PPh 3)2]NO3 (4) can be obtained in excellent yield by the reaction of [(AMTTO)2Ag]NO3 (3) with triphenylphosphane in methanol/acetone. Both complexes were characterized by infrared spectroscopy, elemental analyses as well as by X-ray diffraction studies. Crystal data for 2 at -80°C: space group P1 with a=1233.8(1), b=1389.7(1), c=1417.1(1) pm, α=89.36(1)°; β=65.10(1)°, γ=65.95(1)°, Z=2, R1=0.0582 and for 4 at -80°C: space group P1, with a=1193.3(1), b=1308.5(1), c=1385.3(1) pm, α=94.69(1)°, β=109.14(1)°, γ=93.42(1)°, Z=2, R1=0.0716. Wiley-VCH Verlag GmbH, 2001.