351472-41-8

Basic information

• Product Name: [Ni(Fe(N(CH₂CH₂S)3)(CO)-S,S')2]
• CAS NO: 351472-41-8
• Molecular Weight: 615.137
• Mol File: 351472-41-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ni(Fe(N(CH₂CH₂S)3)(CO)-S,S')2](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(Fe(N(CH₂CH₂S)3)(CO)-S,S')2](351472-41-8)
• EPA Substance Registry System: [Ni(Fe(N(CH₂CH₂S)3)(CO)-S,S')2](351472-41-8)

Safety Data

• Hazardous Substances Data: 351472-41-8(Hazardous Substances Data)

Upstream product

• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 
• 220024-66-8 [NEt₄][Fe(N(CH₂CH₂S)3)(CO)] 

Relevant articles and documents

Targeting synthetic analogues of the metallo-sulfur active sites of nickel enzymes capable of important catalysis

The nickel containing enzymes NiFe-hydrogenase, carbon monoxide dehydrogenase and acetyl-CoA synthase are able to catalyse environmentally, and potentially industrially, important reactions: hydrogen uptake; carbon dioxide/carbon monoxide interconversion; and incorporation of carbon monoxide to form acetyl-CoA, respectively. Progress toward the synthesis of nickel-iron complexes with structural features related to the active sites of these enzymes are described, together with the synthesis, properties and crystal structure of the first methylated-nickel-iron diheterometallic complex, [{Fe(NS3)(NO)-S} Ni(CH3)(dppe)] (NS3 = N(CH2CH2S)33-), relevant to a proposed mechanistic intermediate in the acetyl-CoA synthase mechanism.