351498-01-6Relevant academic research and scientific papers
Regiodirected synthesis of hydroazolic compounds with the use of thiosemicarbazide
Anis'kov, Aleksandr A.,Sazonov, Anton A.,Klochkova, Irina N.
, p. 52 - 53 (2009)
Interaction of α,β-unsaturated ketones of furan series with thiosemicarbazide under basic catalysis leads to 3-furyl-2-thiocarbamoylpyrazolines since nitrous nucleophilic centre of a reagent is activated, whereas the products of intermolecular cyclization
Intramolecular heterocyclization of α,β-unsaturated ketone thiosemicarbazones
Klochkova,Anis'Kov
experimental part, p. 146 - 150 (2009/09/06)
Intramolecular heterocyclization of thiosemicarbazones derived from α,β-enones under acid activation of one nucleophilic center afforded previously unknown 2-(2-arylethenyl)-2,3-dihydro-1,3,4-thiadiazoles. The transformation involves the thiol tautomer of
