35157-91-6Relevant academic research and scientific papers
Synthesis of O-ethyl thioformate: A useful reagent for the thioformylation of amines
Borths, Christopher J.,Chan, Johann,Burke, Brenda J.,Larsen, Robert D.
experimental part, p. 3139 - 3142 (2010/03/24)
O-Ethyl thioformate has been synthesized from triethylorthoformate and hydrogen sulfide gas using a Bronstead acid catalyst. The product can be isolated as a neat liquid in 83% overall yield. Both the crude and purified thiolate can be used to thioformylate a variety of amines in good to excellent yields.
